Abstract Preorganization is a powerful tool in supramolecular chemistry which has been utilized successfully in intra‐ and intermolecular halogen bonding. In previous work. we had developed a bidentate bis(iodobenzimidazolium)‐based halogen bond donor which featured a central trifluoromethyl substituent. This compound showed a markedly increased catalytic activity compared to unsubsti... https://mabelandfoxs.shop/product-category/tea-set/